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Key Points Geochemical evidence suggests that the Mongolian Plateau (MP) is the main source of dust for Lake Tuofengling (TFL) The East Asian Winter Monsoon (EAWM) is likely the dominant carrier of aeolian dust from the MP to TFL Dust flux and EAWM variability could be driven by a combination of changes in ice volume and Atlantic Ocean circulation 

Understanding the movement of fluids in the solid Earth system is crucial for answering a wide range of important questions in Earth science. Boron (B) is a perfect tracer for geofluids because of its high solubility and large isotopic fractionation that depends on both temperature and alkalinity. However, the high volatility of boron in acidic solutions at moderate temperatures presents a significant challenge for accurate measurements of the boron concentration and boron isotopic ratios for silicate rock samples. To circumvent this problem, most laboratories use low-temperature dissolution methods that involve concentrated hydrofluoric acid with or without mannitol. However, hydrofluoric acid is highly hazardous and the controlled temperature condition may be difficult to monitor. As a result, relatively few silicate samples have been analyzed for high precision B concentration and isotopic composition measurements, which hinders our understanding of the behavior of B in the solid earth system and the utility of this powerful tracer. Here we report B concentrations and isotopic compositions of the most commonly used geological reference standards dissolved through sodium peroxide sintering and purified using a rapid single-column exchange chromatographic procedure. This streamlined method effectively removes Na and Si from the sample matrix and generates accurate B concentration and isotopic data in as little as a day without the need for expensive lab equipment and reagents. Sintering is already routinely used to dissolve zircon-bearing silicate samples as it ensures complete dissolution. Besides the analysis of boron, other elemental and isotopic analyses can be performed using aliquots of the same dissolution, which greatly speeds up the chemical processing time and reduces uncertainties associated with sample heterogeneity. Using this method, large amounts of material can be processed for ion-exchange chromatography without the need of splitting each sample into separate beakers for dissolution as is often required for the HF + mannitol dissolution method. This new method can rapidly expand the available dataset of the boron concentration and boron isotopes of silicate materials which will certainly advance our understanding of many geologic problems involving fluids. 

There is a consensus that volcanism along the East African Rift System (EARS) is related to plume activities. However, because of our limited knowledge of the local lithospheric mantle, the dynamics of the plume are poorly constrained by magma chemistry. The Turkana Basin is one of the best places to study plume‐related volcanism because the lithospheric mantle there is unusually thin. New Ar‐Ar geochronology and geochemical data on lavas from western Turkana show that Eocene volcanics have relatively low²⁰⁶Pb/²⁰⁴Pb (<19.1) and high εNd (>3.78). Their relatively high Ba/Rb (35–78) ratios suggest contributions from the shallow lithospheric mantle. Oligo‐Miocene Turkana volcanics have HIMU‐ and EMI‐ type enriched mantle signatures with overall lower Ba/Rb ratios, which is consistent with partial melting of plume material. Pliocene and younger Turkana volcanics have low Ba/Rb and Sr‐Nd‐Pb isotope ratios that resemble those of Ethiopian volcanics with elevated³He/⁴He ratios. This temporal variation can be reconciled with a layered plume model where an outer layer of ancient recycled oceanic crust and sediment overlies more primitive lower mantle material. Beneath Ethiopia, the outer layer of the plume is either missing or punctured by the delamination of the thicker overlying lithospheric mantle atca.30 Ma, an event that would have facilitated the rapid upwelling of the inner portion of the plume and triggered the Ethiopian flood volcanism. The outer layer of the plume may be thicker in the southern EARS, which could explain the occurrence of young HIMU‐ and EMI‐type volcanics with primordial noble gas signatures.

 

The boron (B) memory effect is a concern for B isotope analysis in inductively‐coupled plasma mass spectrometry and a potential cause of poor data comparability between laboratories. It is widely assumed that the memory resides in water droplets on the surface of the spray chamber. However, even without the use of the spray chamber, background subtractions are still required to generate accurate data, therefore additional causes for the memory effect exist, which are investigated here.

Different parts of the mass spectrometer were examined to pinpoint the source of a particularly high B background. After identifying the torch as the source of the background, different parts of the torch were soaked in dilute nitric acid, which was analyzed for B over time.

B was leached out of the tip of the outer quartz tube of the torch in a fashion similar to borosilicate glass, which suggests the incorporation of B into the silica structure of the torch at high temperatures. Running 3% nitric acid washes effectively reduces the background. B background compositions change based on the solutions run beforehand, therefore different blank subtraction methods generate systematic differences. A new background subtraction method that utilizes B isotope ratios improved the precision by up to 0.14‰. The addition of a water wash step before sample elution led to smaller eluent volumes and improved matrix matching without causing a B breakthrough.

An important part of the B memory derives from the torch glass, which incorporates B from sample solutions at high temperatures. Multiple nitric acid washes, matrix matching, blank subtraction, and standard sample bracketing generated accurate B isotope analyses with background/signal ratios as high as 10%, without the need for hazardous chemicals as washes. B isotope values of two sediment standards that represent average post‐Archean continental crust were reported.